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241.使用纤维素和生物油进行酯交换和甲醇合成的耦合过程的可行性研究—最终报告(20100701-20101231)
[化学原料和化学制品制造业,电气机械和器材制造业] [2015-09-02]
Petroleum-based liquid hydrocarbons is exclusively major energy source in the transportation sector. Thus, it is the major CO(sub 2) source which is the associated with greenhouse effect. In the United States alone, petroleum consumption in the transportation sector approaches 13.8 million barrels per day (Mbbl/d). It is corresponding to a release of 0.53 gigatons of carbon per year (GtC/yr), which accounts for approximate 7.6 % of the current global release of CO(sub 2) from all of the fossil fuel usage (7 GtC/yr). For the long term, the conventional petroleum production is predicted to peak in as little as the next 10 years to as high as the next 50 years. Negative environmental consequences, the frequently roaring petroleum prices, increasing petroleum utilization and concerns about competitive supplies of petroleum have driven dramatic interest in producing alternative transportation fuels, such as electricity-based, hydrogen-based and bio-based transportation alternative fuels. Use of either of electricity-based or hydrogen-based alternative energy in the transportation sector is currently laden with technical and economical challenges. The current energy density of commercial batteries is 175 Wh/kg of battery. At a storage pressure of 680 atm, the lower heating value (LHV) of H(sub 2) is 1.32 kWh/liter.
关键词:电池;温室效应;碳氢化合物;可再生能源
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242.PV屋顶适用性评估:方法,专利和验证技术综述
[电力、热力、燃气及水生产和供应业,电气机械和器材制造业] [2015-09-02]
A number of methods have been developed using remote sensing data to estimate rooftop area suitable for the installation of photovoltaics (PV) at various geospatial resolutions. This report reviews the literature and patents on methods for estimating rooftop-area appropriate for PV, including constant-value methods, manual selection methods, and GIS-based methods. This report also presents NREL's proposed method for estimating suitable rooftop area for PV using Light Detection and Ranging (LiDAR) data in conjunction with a GIS model to predict areas with appropriate slope, orientation, and sunlight. NREL's method is validated against solar installation data from New Jersey, Colorado, and California to compare modeled results to actual on-the-ground measurements.
关键词:地理信息系统;空调系统;市场;专利
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243.约瑟夫森数字电路接口的混合约瑟夫森-CMOS随机存取记忆体
[计算机、通信和其他电子设备制造业,电气机械和器材制造业] [2015-09-02]
The work during this period brought our efforts to realize a 64-kbit hybrid Josephson-CMOS memory for 4K operation to a successful conclusion. The memory inputs and outputs are at the several-millivolt level. The inputs are first amplified to 60 mV using Suzuki stacks; these signals drive CMOS comparators, the outputs of which are at volt level, as required by the commercially manufactured 65 nm CMOS memory array. Final designs were fabricated and tested. The access time is less than 400 ps and the read power dissipation is less than 10 mW. A side project was performed to evaluate the concept for a novel wholly Josephson memory proposed by a Japanese memory expert. We found that the proposed memory cell has inadequate design margins. We realized the other goal of the project, which was to analyze the factors limiting Josephson memories. Presentations for the Applied Superconductivity Conference (ASC) in October 2012 were prepared and presented. Publications resulted. We also brought together an international group of 30 cryogenic memory researchers in a post-ASC workshop at UC Berkeley for more discussions. And presentations were made at the Superconductive Electronics Conference (ISEC) in July 2013.
关键词:电路;互补型金属氧化物半导体;低温
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244.选自锌矿产的微量元素地球可用性评估
[采矿业] [2015-09-02]
This assessment focused on five zinc-bearing minerals. The minerals were subjected to a number of analyses including quantitative X-ray diffraction, optical microscopy, leaching tests, and bioaccessibility and toxicity studies. Like a previous comprehensive assessment of five copper-bearing minerals, the purpose of this assessment was to obtain structural and chemical information and to characterize the reactivity of each mineral to various simulated environmental and biological conditions. As in the copper minerals study, analyses were conducted consistent with widely accepted methods. Unless otherwise noted, analytical methods used for this study were identical to those described in the investigation of copper-bearing minerals. Two sphalerite specimens were included in the zinc-minerals set. One sphalerite was recovered from a mine in Balmat, New York; the second came from a mine in Creede, Colorado. The location and conditions of origin are significant because, as analyses confirmed, the two sphalerite specimens are quite different. For example, data acquired from a simulated gastric fluid (SGF) study indicate that the hydrothermally formed Creede sphalerite contains orders of magnitude higher arsenic, cadmium, manganese, and lead than the much older metamorphic Balmat sphalerite. The SGF and other experimental results contained in this report suggest that crystallizing conditions such as temperature, pressure, fluidization, or alteration processes significantly affect mineral propertiesproperties that, in turn, influence reactivity, solubility, and toxicity. The three remaining minerals analyzed for this reportsmithsonite, hemimorphite, and hydrozinciteare all secondary minerals or alteration products of zinc-ore deposits. In addition, all share physical characteristics such as tenacity, density, streak, and cleavage. Similarities end there. The chemical composition, unit-cell parameters, acid-neutralizing potential, and other observable and quantifiable properties indicate very different minerals. Only one of each of these minerals was studied. Had this assessment included multiples of these minerals, geochemical and mineralogical distinctions would have emerged, similar to the results for the two sphalerite specimens.
关键词:校准;化学分析;铜硫化物;发射光谱;无机硫化物
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245.安装在室外机柜的氢系统的安全性—氢气安全专家组
[电气机械和器材制造业,化学原料和化学制品制造业] [2015-09-02]
The Hydrogen Safety Panel brings a broad cross-section of expertise from the industrial, government, and academic sectors to help advise the U.S. Department of Energy's (DOE) Fuel Cell Technologies Office through its work in hydrogen safety, codes, and standards. The Panels initiatives in reviewing safety plans, conducting safety evaluations, identifying safety-related technical data gaps, and supporting safety knowledge tools and databases cover the gamut from research and development to demonstration and deployment. The Panels recent work has focused on the safe deployment of hydrogen and fuel cell systems in support of DOE efforts to accelerate fuel cell commercialization in early market applications: vehicle refueling, material handling equipment, backup power for warehouses and telecommunication sites, and portable power devices. This paper resulted from observations and considerations stemming from the Panels work on early market applications. This paper focuses on hydrogen system components that are installed in outdoor enclosures. These enclosures might alternatively be called cabinets, but for simplicity, they are all referred to as enclosures in this paper. These enclosures can provide a space where a flammable mixture of hydrogen and air might accumulate, creating the potential for a fire or explosion should an ignition occur. If the enclosure is large enough for a person to enter, and ventilation is inadequate, the hydrogen concentration could be high enough to asphyxiate a person who entered the space. Manufacturers, users, and government authorities rely on requirements described in codes to guide safe design and installation of such systems. Except for small enclosures used for hydrogen gas cylinders (gas cabinets), fuel cell power systems, and the enclosures that most people would describe as buildings, there are no hydrogen safety requirements for these enclosures, leaving gaps that must be addressed.
关键词:氢;安全;横截面;部署;电子器件
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246.士官特别任务电池的验证
[电气机械和器材制造业,电力、热力、燃气及水生产和供应业] [2015-09-02]
This report describes research on noncognitive measures for screening Army recruiters with potential application to other Noncommissioned Officer (NCO) assignments. One limitation has been that previously validated instruments for this purpose required proctored testing. To make it easier for Soldiers to be tested, reduce costs, and build upon previous work, ARI was requested to assist with the following: (1) developing a computerized, noncognitive measure suitable for unproctored administration; and (2) validating this instrument against measures of recruiter performance. This new instrument is called the Noncommissioned Officer Special Assignment Battery (NSAB). The NSAB is a computer-adaptive, forced-choice assessment that incorporates recent advances in noncognitive measurement that have been shown to be highly faking resistant and suitable for high-stakes testing environments. The NSAB has 18 scales. Results from a sample of 1,032 experienced Army recruiters indicated that Soldiers with high NSAB composite scores reported the following: (1) lower job stress, and (2) higher satisfaction with recruiting duty. These high-scoring recruiters also were rated by their peers and supervisors as performing better than recruiters with lower NSAB composite scores. These findings indicate that the NSAB can help to identify Soldiers with high potential for recruiting duty success, and it also has the potential for screening in other NCO assignments.
关键词:电池;特殊电池;电池性能
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247.对非结构化网格的基于高阶短特征的确定性运输方法的验证和确认,反应堆概念RD-D
[电气机械和器材制造业,电力、热力、燃气及水生产和供应业] [2015-09-02]
THOR is a radiation transport code that solves the steady-state, multigroup, discrete ordinates approximation of the linear Boltzmann equation in three-dimensional geometry on unstructured tetrahedral cells. The spatial approximation implemented in THOR is the Arbitrarily High Order Transport method of the Characteristic type, AHOTC, extended to Unstructured Grids, AHOTC-UG. The tasks of this project were designed to raise the production level of THOR by supplementing its capabilities then conducting a comprehensive Verification and Validation (V&V) exercise based on Idaho National Laboratory's (INL) Advanced Test Reactor (ATR) configuration and measured data. The primary development work on the code commenced with a study of numerical stability of the underlying equations in the optically-thin cell limit that revealed the cause for the structural instability observed in earlier results. Basically the recursive algorithm used in evaluating the flux spatial moments in terms of lower-order moments accumulated the error to unacceptable magnitude for higher orders. This deficiency was addressed by reformulating the equations and subsequent solution algorithm into a non-recursive form that was found to be numerically stable with increasing spatial expansion order. Additionally we examined the numerical stability of the spatial weights associated with AHOTC-UG and constructed asymptotic expansions that are resilient in the optically thin and thick cell regimes. Many improvements intended to enhance THORs robustness and computational efficiency were implemented, including a cycle-breaking algorithm that may be necessary in some complex automatically-generated unstructured grids.
关键词:四面体;辐射传输;算法;ATR反应器;玻耳兹曼方程
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248.氧化锌纳米线:合成方法和电学性能
[电气机械和器材制造业,化学原料和化学制品制造业] [2015-09-02]
In the present chapter we aim to overview the synthesis techniques and growth mechanism of zinc oxide (ZnO) nanowires and their related properties. In particular, here we review both wet and dry synthesis techniques reported in the literature, such as hydrothermal and sol-gel routes, template-assisted growth, electrodeposition process, chemical vapor deposition (CVD), pulsed laser deposition and RF magnetron sputtering. According to each synthesis technique, the chapter reports not only the detailed procedure, but also the advantages and disadvantages, analyzing in particular the properties of ZnO nanowires related to their microstructural and morphological features. The functional properties of ZnO nanostructures are also overviewed with a particular attention to their electrical properties and the related potential applications, exploiting either the semiconductive and piezoelectric behavior of ZnO nanowires. A comprehensive review is here focused on their use as field effect transistor, energy nanogenerators, pH and gas sensors, as well as the use of ZnO nanowires for energy conversion, like photovoltaic cells and water splitting photoelectrochemical cells.
关键词:电池材料;电解质材料;电学性能
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249.辐射诱导和原子转移自由基聚合相结合的方法制备新型聚合物电解质膜
[电气机械和器材制造业,化学原料和化学制品制造业] [2015-09-02]
The most vital components in polymer electrolyte membrane (PEM) fuel cells are PEM materials. In the case of Nafion (DuPont Co.), the most widely used PEMs, the proton conductivity markedly decreases at high temperature ( > 80 ℃) and low relative humidity (RH) ( < 30%). This drawback limits the use of Nafion in practical and commercial applications. Our research group is developing the Nafion-alternative PEMs by using a radiation-induced grafting method1'. In these PEMs, the graft chain structures should significantly affect the proton conduction properties. Then, in this study, by combination of radiation grafting and atom transfer radical polymerization (ATRP), we designed the novel PEMs possessing both the hydrophobic and hydrophilic graft chains.
关键词:燃料电池;辐射诱导;电解质膜
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250.自动敷设快速洪水淹没模型
[电力、热力、燃气及水生产和供应业,电气机械和器材制造业] [2015-09-02]
This Coastal and Hydraulics Engineering Technical Note (CHETN) demonstrates the flood modeling capabilities of the AutoRoute model. The AutoRoute model has been developed to support the Military Hydrology Program at the Coastal and Hydraulics Laboratory (CHL) as part of their mission to determine route vulnerability caused by flooding over large land areas. Through several tests the AutoRoute model showed that it quickly and effectively simulates the flood extent of high flow volumes where adequate Digital Elevation Model (DEM) data is available. The Military Hydrology Program at CHL fields numerous requests for information (RFI) from the military regarding route vulnerability caused by hydrologic factors, such as flooding. Currently, completing these route vulnerability studies includes the use of the AutoRoute model developed by CHL personnel in 2011. The model is computationally efficient and versatile, allowing for large sections of routes to be analyzed in a timely fashion. The model results can also link to existing mobility models to determine the risk that flooding has on the mobility of vehicles. The AutoRoute model is a one-dimensional, raster-based program developed to determine flood extent and stream cross sections efficiently over large areas. The model uses a Digital Elevation Model (DEM) and a computed stream mask to determine the location and cross section of each stream cell within the domain. As in most modeling cases, the finer the resolution of the DEM data, the more accurate and defined the results will be. The goal of AutoRoute is to compute the inundated area and spatially explicit depth of inundation for a given flow value. For a given flow Q we wish to derive the flood depth h, flood extent, cross-section profile, cross-section area A, and average flow velocity (V = Q/A). Unlike typical flood models, the AutoRoute model neglects the flow in highly detailed channels.
关键词:计算机程序;洪水;横截面;液压系统