While examining fuel-reforming technology for fuel cells onboard aircraft, Glenn Research Center partnered with Garrettsville, Ohio-based Catacel Corporation through the Glenn Alliance Technology Exchange program and a Space Act Agreement. Catacel developed a stackable structural reactor that is now employed for commercial hydrogen production and results in energy savings of about 20 percent.

关键词：燃料电池；能量流失；能源节省

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Oxygen reduction reaction (ORR) is important in fuel cells. Although platinum nanoparticles can catalyse the ORR in an efficient way, the high cost of the platinum catalysts, together with its limited reserves in nature, has been shown to be the major 'showstopper' to mass market fuel cells for commercial applications. Following our earlier work on metal-free, nitrogen- doped carbon nanotubes (Gong, K.; Du, F.; Xia, Z.; Durstock, M.; Dai, L. Science 2009, 323, 760) and nitrogen-doped graphene sheets (Qu, L.; Liu, Y.; Baek, J.-B.; Dai, L. ACS Nano 2010, 4, 1321) as highly efficient ORR, we have developed in this project new metal-free and oxygen-free graphene materials by either edge-functionalization or ball milling as efficient electrocatalysts for ORR in fuel cells and other applications, including dye-sensitized solar cells (DSSCs).

关键词：催化剂；燃料电池；石墨烯；纳米科学与技术

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Energy availability and long term operation are key challenges for wireless sensor networks and for all the applications where the devices are battery operated. For this reason energy harvesting is becoming very important for powering ubiquitously deployed sensor networks and mobile electronics. One of most important goal for the next generation of power supply units for standalone embedded systems is to power nearly perpetually the devices when the scavenger is exposed to reasonable environmental energy conditions. However, due to the unpredictable nature of the environmental sources, prolonged lacks of energy intake usually happen. The last frontiers of perpetual operating systems is combining different energy harvesters in a single unit and using green energy supply with high energy density as micro hydrogen fuel cells. In this paper we introduce a Smart Power Unit (SPU) for embedded system which incorporates energy harvesters from sun and wind and uses hydrogen fuel cell as alternative energy storage. The power unit can work as a long-term battery or providing serial communication to exchange power information and to perform power management. In fact the core of the SPU is an ultra low power micro controller which is in charge to do the power activities such as Maximum Power Point Tracking for the harvesters, fuel cell activation, energy prediction, adaptive power management on board, battery monitoring and communications with powered systems. Experimental results and simulations shows the high efficiency (up to 90 %) of the power conversion subsystem. Finally a real deployment in a structural health monitoring site in Switzerland shows as the energy neutral condition is achieved on field.

关键词：氢电池；电动收割机；户外应用

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In an effort to understand and quantify the carbon and sulfur contents of a curium oxide production process performed in the hot cells at Oak Ridge National Laboratory's Radiochemical Engineering Development Center, a non-radioactive surrogate was used in a similar oxide formation process. Neodymium (Nd), which was chosen as a substitute for curium, was loaded onto a Dowex 50W-X8 resin by use of ion exchange column techniques and then treated under a variety of processing conditions. The surrogate product was analyzed for carbon and sulfur impurities, using inductively coupled plasma-mass spectrometry for sulfur assessment, a LECO combustion furnace/analyzer for carbon quantification, and X-ray diffraction for compound identification. The results indicate that the carbon and sulfur contents in the Nd oxide were similar to current estimations for curium oxide using the reference hot cell process. It was also seen that the major surrogate product of the hot cell process contained sulfur in a Nd oxysulfate (Nd2O2SO4) compound. Parametric analysis of the resin decomposition process revealed that increasing the temperature to 1400 degrees C yielded considerably better removal of carbon and sulfur.

关键词：钕；树脂；碳； Curicum氧化；分解；热电池

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As a first step towards a microscopic understanding of single-Pt atom-dispersed catalysts on non-conventional TiN supports, we present density- functional theory (DFT) calculations to investigate the adsorption properties of Pt atoms on the pristine TiN(100) surface, as well as the dominant influence of surface defects on the thermodynamic stability of platinized TiN. Optimized atomic geometries, energetics, and analysis of the electronic structure of the Pt/TiN system are reported for various surface coverages of Pt. We find that atomic Pt does not bind preferably to the clean TiN surface, but under typical PEM fuel cell operating conditions, i.e. strongly oxidizing conditions, TiN surface vacancies play a crucial role in anchoring the Pt atom for its catalytic function. Whilst considering the energetic stability of the Pt/TiN structures under varying N conditions, embedding Pt at the surface N-vacancy site is found to be the most favorable under N-lean conditions. Thus, the system of embedding Pt at the surface N-vacancy site on TiN(100) surface could be a promising catalyst for PEM fuel cells.

关键词：吸附原子；燃料；缺陷（材料）

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Numerical simulation capabilities to perform flowfield analysis and sensitivity analysis of solid oxide fuel cells (SOFCs) have been developed. A three-dimensional, implicit, multi-species fuel cell solver is modified to analyze cell geometries supplied by NexTech Materials (NexTech). Four different NexTech cell configurations of varying complexities have been analyzed in this study. A capability to perform thermo-mechanical analysis of NexTech cells is developed by coupling the fuel cell code with the structures code. The capability was initially developed for a simplified cell that also included sensitivity analysis of thermo-mechanical variables. Sensitivity derivatives are computed using the direct differentiation method in the fuel cell and structures codes.

关键词：燃料电池；氧化物；平面结构；耦合（互动）

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We deployed a 855 cm2 thin-film, single-junction gallium arsenide (GaAs) photovoltaic (PV) module outdoors. Due to its fundamentally different cell technology compared to silicon (Si), the module responds differently to outdoor conditions.

关键词：光伏电池；镓砷化物；薄膜；砷化镓太阳能电池

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Active DMFCs require complicated balance of plant to ensure recirculation of unreacted methanol and internally produced water as well as venting of exhaust gases. An alternative approach is redesign of the fuel delivery system to accommodate concentrated methanol that is consumed entirely within the fuel cell, thus removing the need for recirculation. A specialized anodic porous structure was designed which the dual role of flowfield and diffusion medium for concentrated methanol. In addition, a highly hydrophobic gas diffusion media were used at the DMFC cathode to prevent water loss by promoting water back-diffusion to the anode. This internally dilutes the methanol and enables use of highly concentrated methanol. The anodic porous structure used in concert with the hydrophobic cathode diffusion medium led to gross fuel energy densities of the operating cell of ca. 845 W*hr/Lfuel and fuel utilization in excess of 70%. A small 2 cell stack was built and successfully operated to verify that the concept is scalable. The hydrophobicity of the cathode diffusion layer is of vital importance for this concept and research for improved materials that will reduce water loss even more is still ongoing using internal funds. The project also funded student research at Northeastern University and at Inter American University in Puerto Rico. This hardware based program complemented an IFDL modeling program sponsored by the DOE.

关键词：阴极；甲醇燃料电池；电动电池；电化学

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The National Renewable Energy Laboratory (NREL), in association with the U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy (EERE), held a Biogas and Fuel Cells Workshop on June 11-13, 2012, in Golden, Colorado, to discuss biogas and waste-to-energy technologies for fuel cell applications. The meeting was spearheaded by the Fuel Cell Technologies Program in coordination with the Biomass Program. The overall objective was to identify opportunities for coupling renewable biomethane with highly efficient fuel cells to produce electricity; heat; combined heat and power (CHP); or combined heat, hydrogen and power (referred to as CHHP or trigeneration) for stationary or motive applications. The workshop focused on biogas sourced from wastewater treatment plants (WWTPs), landfills, and industrial facilities that generate or process large amounts of organic waste, including large biofuel production facilities (biorefineries).

关键词：生物质燃料；燃料电池；厌氧消化；沼气

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Energy availability and long term operation are key challenges for wireless sensor networks and for all the applications where the devices are battery operated. For this reason energy harvesting is becoming very important for powering ubiquitously deployed sensor networks and mobile electronics. One of most important goal for the next generation of power supply units for standalone embedded systems is to power nearly perpetually the devices when the scavenger is exposed to reasonable environmental energy conditions. However, due to the unpredictable nature of the environmental sources, prolonged lacks of energy intake usually happen. The last frontiers of perpetual operating systems is combining different energy harvesters in a single unit and using green energy supply with high energy density as micro hydrogen fuel cells. In this paper we introduce a Smart Power Unit (SPU) for embedded system which incorporates energy harvesters from sun and wind and uses hydrogen fuel cell as alternative energy storage. The power unit can work as a long-term battery or providing serial communication to exchange power information and to perform power management. In fact the core of the SPU is an ultra low power micro controller which is in charge to do the power activities such as Maximum Power Point Tracking for the harvesters, fuel cell activation, energy prediction, adaptive power management on board, battery monitoring and communications with powered systems. Experimental results and simulations shows the high efficiency (up to 90 %) of the power conversion subsystem. Finally a real deployment in a structural health monitoring site in Switzerland shows as the energy neutral condition is achieved on field.

关键词：氢燃料电池；能源供应；永久操作系统

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