关键词:电池能源;光热光谱分析;等离子体
摘 要:The aluminum nanoparticles (Al NPs) are demonstrated to serve as active photothermal media, to enhance and control local photothermal energy deposition via the photothermal effect activated by localized surface plasmon resonance (LSPR) and amplified by Al NPs oxidation. The activation source is a 2-AA-battery-powered xenon flash lamp. The extent of the photothermally activated movement of Al NPs can be approx. 6 mm. Ignition delay can be approx. 0.1 ms. Both scanning electron microscopy and energy-dispersive X-ray spectroscopy measurements of motion-only and after-ignition products confirm significant Al oxidation occurs through sintering and bursting after the flash exposure. Simulations suggest local heat generation is enhanced by LSPR. The positive- feedback effects from the local heat generation amplified by Al oxidation produce a large increase in local temperature and pressure, which enhances movement and accelerates ignition.