关键词：传感器；光学探测器；基地（化学）；二氧化碳；泵；海洋监测；海洋数据采集系统
摘 要：The novelly designed optical sensor for autonomous ocean monitoring works on equilibrium principles. When the pH-sensitive reagent solution sitting behind a gas-permeable membrane is exposed to seawater, the CO2 molecules present in the seawater diffuse across the membrane into the reagent and induce a pH change. After equilibrium is reached, the fluorescence is measured and the pCO2 data are recovered from a calibration curve. A specific feature of our measurement technique is the use of excitation ratiometric approach. A violet LED (Light Emitting Diode) and a blue LED are used to excite the sensing reagent through an excitation filter and the pCO2 dependent emission is measured through an emission filter by a photodiode.