关键词：加氢；可逆；石墨烯
摘 要：We use x-ray spectroscopy and density functional theory to investigate the hydrogenation-induced electronic structure changes in graphene on Pt(111). The atom-specific properties of the spectroscopy allow for a direct projection of the band structure onto the carbon atoms; this was compared with the calculated density of states. Instead of the generally expected band opening behavior, we observe states at the Fermi level in the carbon-projected density of states. Hydrogenation is accompanied by pinning of the graphene to the substrate through the formation of local CPt bonds which cause the graphene layer to become metallic upon hydrogenation.