关键词：电子信息；半导体；太阳能；光阳极
摘 要：CdSe quantum dot (QD)-sensitized solar cells (QDSCs) were synthesized by adsorbing CdSe QDs onto TiO_2 nanostructured electrodes with different morphologies, i.e., nanoparticles, nanotubes, and inverse opals. The optical absorption, photoelectrochemical, and photovoltaic properties of the QDSCs were characterized and the dependences of these properties on the QD deposition time and the TiO_2 nanostructure are discussed. To improve the photovoltaic performance of the CdSe QDSCs, surface passivation with a ZnS coating was introduced and CU_2S counter electrodes were applied. All aspects of the photovoltaic performance, including the short-circuit photocurrent density, open-circuit voltage, fill factor, and efficiency, were found to be significantly improved by the surface modification with ZnS. For the counter electrode, the Cu_2S electrode was demonstrated to be more efficient than platinum against the polysulfide electrolytes usually used as redox couples in CdSe QDSCs. Moreover, CdS QD adsorption on the TiO_2 electrodes prior to CdSe QD adsorption also resulted in better solar cell performance. In addition, we found that the morphology of the TiO_2 electrodes had a great influence on the photovoltaic properties of the QDSCs. Finally, a power conversion efficiency as high as 4.9was achieved for a combined CdS/CdSe QDSC under solar illumination of 100 mW/cm~2.