使用离子液体催化生物质转化为燃料和化学品的研究
Catalytic Conversion of Biomass to Fuels and Chemicals Using Ionic Liquids
作者:Liu, W.;Zheng, R.;Brown, H.;Li, J.;Holladay, J.;Cooper, A.;Rao, T.
作者单位:Pacific Northwest National Lab., Richland, WA.;Department of Energy, Washington, DC.
加工时间:2014-03-27
信息来源:科技报告(DE)
索取原文[54 页]
关键词:生物质能;催化作用;生物质转化;燃料;碳纤维
摘 要:This project provides critical innovations and fundamental understandings that enable development of an economically-viable process for catalytic conversion of biomass (sugar) to 5-hydroxymethylfurfural (HMF). A low-cost ionic liquid (Cyphos 106) is discovered for fast conversion of fructose into HMF under moderate reaction conditions without any catalyst. HMF yield from fructose is almost 100on the carbon molar basis. Adsorbent materials and adsorption process are invented and demonstrated for separation of 99pure HMF product and recovery of the ionic liquid from the reaction mixtures. The adsorbent material appears very stable in repeated adsorption/regeneration cycles. Novel membrane-coated adsorbent particles are made and demonstrated to achieve excellent adsorption separation performances at low pressure drops.