石墨烯稳定的基因工程病毒M13为模板框架开展混合动力储能材料
Graphene Sheets Stabilized on Genetically Engineered M13 Viral Templates as Conducting Frameworks for Hybrid Energy-Storage Materials
关键词:储能;混合动力系统;原子结构;生物分子;晶体结构;活性材料;传感器;基因工程
摘 要:Single-layer graphene sheets have significantly broadened the horizon of nanotechnology with the unique electronic, optical, quantum mechanical and mechanical properties associated with the two-dimensional atomic crystal structure. To best utilize this material for practical applications, it is crucial to prevent the spontaneous aggregation between individual graphene sheets while composite materials are formed. Numerous efforts have been made to stabilize functionalized graphene sheets on molecular or polymeric species. Biomolecules such as DNA and proteins have also been grafted onto graphene planes and used for biosensors, controlled drug-delivery as well as cancer imaging. As well as biomedical applications, graphene sheets can also be hybridized with biomolecules into energy-storage devices to increase the conductivity of the active materials that are often insulators. In previous work, ultrasonication or chemical reduction, followed by heat treatment, have been adopted to achieve composites between graphene and various materials (e.g., LiFePO4 and SnO2). However, due to the non-specific nature of the interactions between the graphene templates and active materials, it is expected that only random and inhomogeneous contacts are created, leaving the segregation on nano- or even sub-micrometer levels.