关键词:纳米复合材料;半导体;聚合物;光致发光
摘 要:Recently, organic-inorganic hybrid nanocomposite materials have been of great interest for their extraordinary performances due to the combination of the advantageous properties of polymers and the size dependent properties of nanocrystals (NCs). Interaction between the polymer matrix and nanocrystalline fillers produces wonderful features, viz. thermal, magnetic, mechanical, electrical and optical properties to these materials. Modern applications require a new design of responsive functional coatings which is capable of changing their properties in a controlled way. However, the synthesis of Ⅱ-Ⅵ nanoparticles into the polymer matrix of its nanocomposites with adjustable sizes and protected from photo-oxidation is a big challenge to the scientific community. It is difficult to synthesize the highly enhanced luminescence in polymers and its semiconductor nanocomposite systems. Luminescence from the polymer embedded Ⅱ-Ⅵ nanoparticles is greatly enhanced and better stability can be achieved from the composite compared to bulk materials. The formation of nanocomposites can be confirmed by photoluminescence (PL) spectroscopy. It is an important technique for determining the optical gap, purity, crystalline quality defects and analysis of the quantum confinement in these nanocomposite materials. In this paper, we have reviewed the present status of Ⅱ-Ⅵ polymer nanocomposites from the photoluminescence studies point of view. We have also shown the results of the PL of these nanocomposite materials and the results will be compared with the reported literature by other groups.