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使用光还原法的聚四氟乙烯工业废水中全氟化碳的消除

Abatement of perfluorocarbons in Teflon-mannufacturing wastewater with photo-reduction method

作者:Chaojie Zhang;Geng Zhang;Pei Chen ;Yan Qu;Qi Zhou 作者单位:Key Laboratory of Pollution Control and Resource Reuse College of Environmental Science and Engineering, Tongji University, Shanghai, P.R.China 加工时间:2015-07-15 信息来源:科技报告(other) 索取原文[4 页]
关键词:节能;水合电子;全氟化碳;氟化工厂;光还原法
摘 要:Decomposition and defluorination of PFCs in wastewater by photo-induced hydrated electrons was well and firstly investigated in this paper.In this work the proposed method was tested to deal with PFCs containing wastewaters from a Teflon-manufacturing plant in Jiangsu Province, China.95.5% of perfluorooctanoic acid (PFOA) was decomposed after 12 hours treatment and defluorination rate of PFCs could reach about 60%.PFCs were transformed into harmless fluoride, acetic acid and formic acid.It was suggested this system can efficiently decompose PFCs from fluorine chemical plant.In brief, this study demonstrates that the photo-reduction is a high efficient, energy-saving method which produced less-toxic products for PFCs removal, compared with activated carbon absorption and combustion.
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