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从生物质基糠醛聚酯合成生物质基单体的研究及其生物质碳比率评估
Synthesis of Biomass-Based Monomers from Biomass-Based Furfural for Polyesters and Evaluation of Their Biomass Carbon Ratios
作者:Yuya Tachibana;Takashi Masuda;Masahiro Funabashi;Ken-ichi Kasuya;Masao Kunioka 作者单位:Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University, 1-5-1 Tenjin, Kiryu, Gunma 376-8515, Japan 加工时间:2014-03-26 信息来源:科技报告(other) 索取原文[20 页]
关键词:生物质能;糠醛;生物质基单体;碳比率
摘 要:Fully biomass-based poly(butylene succinate) (PBS) was obtained by polycondensation of biomass-based 1,4-butanediol and biomass-based succinic acid or dimethyl succinate. Succinic anhydride (SAn) and tetrahydrofuran (THF) were also synthesized from furfural. Fully biomass-based poly(butylene oxide-co-butylene succinate) was obtained by ring-opening polymerization of biomass-based SAn and THF. Partially biomass-based poly(butylene terephthalate) was obtained by polycondensation of biomass-based 1,4-butanediol and petroleum-based terephthalic acid. The biomass carbon ratio calculated from ~(14)C concentrations measured by accelerator mass spectroscopy verified that the PBS obtained in this study contained only biomass carbon.
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