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增强快速热解油稳定性的方法:后处理(最终报告)
UOP LLC, a Honeywell Company, assembled a comprehensive team for a two-year project to demonstrate innovative methods for the stabilization of pyrolysis oil in accordance with DOE Funding Opportunity Announcement (FOA) DE-PS36-08GO98018, Biomass Fast Pyrolysis Oil (Bio-oil) Stabilization. In collaboration with NREL, PNNL, the USDA Agricultural Research Service (ARS), Pall Fuels and Chemicals, and Ensyn Corporation, UOP developed solutions to the key technical challenges outlined in the FOA. The UOP team proposed a multi-track technical approach for pyrolysis oil stabilization. Conceptually, methods for pyrolysis oil stabilization can be employed during one or both of two stages: (1) during the pyrolysis process (In Process); or (2) after condensation of the resulting vapor (Post-Process). Stabilization methods fall into two distinct classes: those that modify the chemical composition of the pyrolysis oil, making it less reactive; and those that remove destabilizing components from the pyrolysis oil. During the project, the team investigated methods from both classes that were suitable for application in each stage of the pyrolysis process. The post processing stabilization effort performed at PNNL is described in this report.
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生物气燃料电池研讨会总结报告(2012.6.11——2012.6.13)
The National Renewable Energy Laboratory (NREL), held a Biogas and Fuel Cells Workshop on June 11-13, 2012, in Golden, Colorado, to discuss biogas and waste-to-energy technologies for fuel cell applications. The meeting was spearheaded by the Fuel Cell Technologies Program in coordination with the Biomass Program. The overall objective was to identify opportunities for coupling renewable biomethane with highly efficient fuel cells to produce electricity; heat; combined heat and power (CHP); or combined heat, hydrogen and power. The workshop focused on biogas sourced from wastewater treatment plants (WWTPs), landfills, and industrial facilities that generate or process large amounts of organic waste, including large biofuel production facilities (biorefineries).
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纳米级植物细胞壁结构实时成像技术,有关纤维素酶易得性及降解的动力学分析
Presentation on real-time imaging of plant cell wall structure at nanometer scale. Objectives are to develop tools to measure biomass at the nanometer scale; elucidate the molecular bases of biomass deconstruction; and identify factors that affect the conversion efficiency of biomass-to-biofuels.
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从生物质合成气合成生物燃料的纳米催化剂研究
The potential silica nanospring (NS) supported cobalt catalyst (Co/SiO2-NS) for Fischer-Tropsch synthesis (FTS) was investigated, and the results were compared with those of a conventional silica gel supported cobalt catalyst (Co/SiO2-gel). Co/SiO2-gel and Co/SiO2-NS catalysts were prepared using the incipient wetness impregnation method and a thermal assisted reduction process, respectively, and characterized by scanning electron microscopy/ energy dispersive spectroscopy (SEM/EDS), transmission electron microscopy (TEM), N2 physisorption, X-ray powder diffraction (XRD), and H2-temperature programed reduction (H2-TPR). The catalysts were evaluated for their conversion of syngas to products in a quartz fix-bed micro-reactor (230 DGC, atm pressure). The FTS products were trapped and characterized by GC-MS to determine conversion efficiency. The products (alkanes) for both catalysts ranged from C1 to C21 and would be a suitable substrate for diesel. The results show that the NS approach for a FTS catalyst support shows promise for generating fuels from syngas.
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长期议题(2012):农民的选择与生物燃料的未来
This paper focuses on the patterns of farmers choices regarding dedicated perennial lignocellulosic energy crops. Throughout this paper we use the term perennial as shorthand for warm season grasses such as those in the genus Panicum or Miscanthus, or short rotation tree crops such as those in the genus Populus or Salix. We focus on choices about these perennial crops because two thirds of the mandated advanced biofuels are expected to be converted at biorefineries from perennials (USDA 2010). RFS2 establishes the goals, but not mechanisms for achieving them. Mechanisms and incentives, however, are embedded in other legislation and programs.
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使用离子液体催化生物质转化为燃料和化学品的研究
This project provides critical innovations and fundamental understandings that enable development of an economically-viable process for catalytic conversion of biomass (sugar) to 5-hydroxymethylfurfural (HMF). A low-cost ionic liquid (Cyphos 106) is discovered for fast conversion of fructose into HMF under moderate reaction conditions without any catalyst. HMF yield from fructose is almost 100on the carbon molar basis. Adsorbent materials and adsorption process are invented and demonstrated for separation of 99pure HMF product and recovery of the ionic liquid from the reaction mixtures. The adsorbent material appears very stable in repeated adsorption/regeneration cycles. Novel membrane-coated adsorbent particles are made and demonstrated to achieve excellent adsorption separation performances at low pressure drops.
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使用加氢热解和加氢转化技术将生物质转化为汽油和柴油的研究(报告期:2010.4.1——2012.12.1)
These studies show when using IH2 technology, biomass can be converted directly to transportation quality fuel blending components for the same capital cost required for pyrolysis alone, and a fraction of the cost of pyrolysis plus upgrading of pyrolysis oil. Technoeconomic work for IH2 and lifecycle analysis (LCA) work has also been completed as part of this DOE study and shows IH2 technology can convert biomass to gasoline and diesel blending components for less than $2.00/gallon with greater than 90reduction in greenhouse gas emissions. As a result of the work completed in this DOE project, a joint development agreement was reached with CRI Catalyst Company to license the IH2 technology.
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生物燃料的模拟和区域分析的国家地质数据库设计
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木质纤维素生物质原料性质对内生真菌VOC属性的改变
Endophytic fungi have been shown to produce a range of moderate-molecular weight hydrocarbons (volatile organic compounds-VOC) directly from cellulosic biomass without any pretreatment. These organisms have the capacity to alter their VOC profile as a function of carbon source. We cultured a number of these fungi on potential biofuel biomass (corn stove, eucalyptus and switchgrass) as the sole carbon source and their growth rates were compared to potato dextrose agar. We then performed a VOC profile of the biomass-supported fungal cultures. Our findings are an important first step in developing industrial hosts (microbes or fungi) with both biomass deconstruction and fuel synthesis pathways.
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利用奶牛和肉牛畜牧生产的可再生能源及环境的可持续发展.卷1:热化学转化与直接燃烧法
Manure-based biomass (MBB) has the potential to be a source of green energy at large coal-fired power plants and on smaller-scale combustion systems at or near confined animal feeding operations. Although MBB particularly cattle biomass (CB) is a low quality fuel with an inferior heat value compared to coal and other fossil fuels, the concentration of it at large animal feeding operations can make it a viable source of fuel. The overall objective of this interdisciplinary proposal is to develop environmentally benign technologies to convert low-value inventories of dairy and beef cattle biomass into renewable energy. Current research expands the suite of technologies by which cattle biomass (CB: manure, and premature mortalities) could serve as a renewable alternative to fossil fuel.