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新兴能源技术中的二氧化钛纳米结构
Titanium dioxide has been used as the white pigment since the ancient times.95% of its current usage in industry involves paints, cosmetics, plastics, paper, and food. However, in near future the economic impact of titanium dioxide seems to be controlled by energy related applications mostly. Therefore, this chapter projects a brief outlook on the added value provided by the titanium dioxide structures in new and emerging technologies of the energy sector. The applications focused are: solar fuels, solar cells, fuel cells, Li ion batteries and solid state lighting. In those applications, TiO_2 standouts with its chemical and thermal stability, morphology variety, position of conduction and valance band energy levels, optical properties and cost.
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使用纤维素和生物油进行酯交换和甲醇合成的耦合过程的可行性研究—最终报告(20100701-20101231)
Petroleum-based liquid hydrocarbons is exclusively major energy source in the transportation sector. Thus, it is the major CO(sub 2) source which is the associated with greenhouse effect. In the United States alone, petroleum consumption in the transportation sector approaches 13.8 million barrels per day (Mbbl/d). It is corresponding to a release of 0.53 gigatons of carbon per year (GtC/yr), which accounts for approximate 7.6 % of the current global release of CO(sub 2) from all of the fossil fuel usage (7 GtC/yr). For the long term, the conventional petroleum production is predicted to peak in as little as the next 10 years to as high as the next 50 years. Negative environmental consequences, the frequently roaring petroleum prices, increasing petroleum utilization and concerns about competitive supplies of petroleum have driven dramatic interest in producing alternative transportation fuels, such as electricity-based, hydrogen-based and bio-based transportation alternative fuels. Use of either of electricity-based or hydrogen-based alternative energy in the transportation sector is currently laden with technical and economical challenges. The current energy density of commercial batteries is 175 Wh/kg of battery. At a storage pressure of 680 atm, the lower heating value (LHV) of H(sub 2) is 1.32 kWh/liter.
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DWPF还原剂替代模拟,乙醇酸和消泡剂747的有机物性质
The present study examines the fate of glycolic acid and other organics added in the Chemical Processing Cell (CPC) of the Defense Waste Processing Facility (DWPF) as part of the glycolic alternate flowsheet. Adoption of this flowsheet is expected to provide certain benefits in terms of a reduction in the processing time, a decrease in hydrogen generation, simplification of chemical storage and handling issues, and an improvement in the processing characteristics of the waste stream including an increase in the amount of nitrate allowed in the CPC process. Understanding the fate of organics in this flowsheet is imperative because tank farm waste processed in the CPC is eventually immobilized by vitrification; thus, the type and amount of organics present in the melter feed may affect optimal melt processing and the quality of the final glass product as well as alter flammability calculations on the DWPF melter off gas. To evaluate the fate of the organic compounds added as the part of the glycolic flowsheet, mainly glycolic acid and antifoam 747, samples of simulated waste that was processed using the DWPF CPC protocol for tank farm sludge feed were generated and analyzed for organic compounds using a variety of analytical techniques at the Savannah River National Laboratory (SRNL). These techniques included Ion Chromatography (IC), Gas Chromatography-Mass Spectrometry (GC-MS), Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES), and Nuclear Magnetic Resonance (NMR) Spectroscopy.